Lithium-doped aluminum cluster anions, LiAln- were generated in a laser vaporization source and examined via mass spectrometry and anion photoelectron spectroscopy (n=3-15). The mass spectrum of the LiAln- series exhibits a local minimum in intensity at n=13. The electron affinity vs cluster size trend also shows a dip at n=13. Agreement is quite good between our measured electron affinity values and those calculated by Rao, Khanna, and Jena, suggesting that their predictions about the structure and bonding of LiAl13 and other clusters in this series are also largely valid.