화학공학소재연구정보센터
Journal of Chemical Physics, Vol.114, No.3, 1286-1294, 2001
Investigations of pure rotational transitions of H-2 perturbed by He. II. High-temperature calculations and extrapolations
Close-coupling calculations of broadening and shifting coefficients of Raman S-0(j) lines of H-2 perturbed by He are performed up to 3000 K. They are used to test two approximate methods, the quantum coupled states theory and the RB semiclassical model. They are further applied to study the use of simple functional forms for fitting and extrapolating experimental data, and some new fits of experimental broadening coefficients are given.