Journal of Chemical Physics, Vol.113, No.21, 9772-9777, 2000
Critical behavior of simple fluids confined by microporous materials
a cubic lattice with nearest-neighbor interactions. A small fraction of the lattices sites are blocked, thereby creating a quenched matrix. Histogram reweighting techniques are applied to investigate the critical behavior of the system. We have studied lattice sizes ranging from L = 10 to L = 18. For each size, we have evaluated the number of matrix replicas necessary to obtain statistically meaningful results. This number, determined by analyzing the convergence of the histograms, ranged from 50 for the smallest system sizes to 200 for the largest sizes. We have evaluated the critical temperature, the fourth cumulant of Binder et nl. [K. K. Kaski, K. Binder, and J. D. Gunton, Phys. Rev. B 29, 3996 (1984)], and the critical exponents 1/(l ') and beta/nu. The estimated critical temperature is only slightly lower than that of the three-dimensional Ising model. The simulated critical exponents, however, differ significantly from those for Ising-class three-and two-dimensional systems.