In this paper we calculate the 64 potential energy surfaces of the manifold of states of I-3 that dissociate to three ground state iodine radicals as functions of bend and stretching coordinates. We describe the set of quantum rotations necessary to generate the full Hamiltonian matrix using only I-2 experimental energies and describe the formal connection between this approach and the usual diatomic in molecules Hamiltonian formulation. The I-3 excited state surfaces calculated in this way are used to compute various excited state features in the photoelectron spectrum of I-3(-) and we use these results to interpret the recently measured spectrum.