화학공학소재연구정보센터
Journal of Chemical Physics, Vol.111, No.20, 9441-9445, 1999
Effect of competition between catalytic particles C on the rate of the reversible diffusion-controlled reaction A+C reversible arrow B+C
The effect of competition between catalytic particles C on the rate of the reversible diffusion-controlled reaction A+reversible arrow B+C is studied in a self-consistent approximation. The C-particles are assumed static with random configuration. The A- and B-particles diffuse in a fluid or solid background medium. Frequency-dependent effective rate coefficients are calculated as a function of the volume fraction of C-particles.