화학공학소재연구정보센터
Journal of Chemical Physics, Vol.111, No.14, 6238-6246, 1999
Ultrafast extended x-ray absorption fine structure (EXAFS) -theoretical considerations
Inspired by the recent experimental demonstration of ultrafast x-ray absorption spectroscopy, we present a framework for the calculation of extended x-ray absorption fine structure (EXAFS) spectra on the ultrafast (femtosecond to picosecond) time scale. Model calculations for gas phase I-2, evolving under the influence of laser pumping, demonstrate that ultrafast EXAFS has the potential to serve as a direct probe of nuclear dynamics, including time-dependent interatomic separations and relative orientations. The feasibility of ultrafast EXAFS as a viable and useful experimental technique is discussed.