Journal of Chemical Physics, Vol.111, No.13, 5641-5644, 1999
The influence of polymer on the diffusion of a spherical tracer
We analyze how the addition of a small number of polymer molecules influences the diffusion constant of a spherical tracer, whose radius is small compared to the size of the polymer. We show that the polymer chain can be regarded as a two-dimensional object which is an impenetrable obstacle for the tracer. It is also shown that the diffusion constant of the tracer, in contrast to the solution viscosity, is independent of chain length, depending only on the monomer concentration.