화학공학소재연구정보센터
Journal of Chemical Physics, Vol.111, No.12, 5544-5554, 1999
van der Waals theory for the spatial distribution of the tension in an interface. I. Density functional theory
The van der Waals theory for the thermodynamic properties of equilibrium fluids is usually presented as an example of a mean field approximation to a simple interaction model. We use density functional arguments to show that the van der Waals description can also be viewed as an exact consequence of a more complex interaction model. The relation to standard statistical mechanical quantities is constructed and the theory is used to determine the tension profile at a vapor-liquid-wall interface.