Journal of Chemical Physics, Vol.111, No.4, 1541-1550, 1999
Dielectric behavior of ferroelectric liquid crystals in the vicinity of the transition into the hexatic phase
Collective molecular dynamics was studied in ferroelectric smectic C-* and hexatic smectic I-* phases by the dielectric method. In the frequency range 1 Hz to 10 MHz one relaxation process was observed in both phases. In the SmC* phase the relaxation frequency of this process linearly decreases and its dielectric strength increases when approaching the SmC*-SmI* phase transition temperature T-I. In the SmI* phase the relaxation frequency is one order of magnitude lower and further slightly decreases on cooling. A phenomenological theory has been developed which describes static and dynamic dielectric properties near T-I and satisfactorily explains the experimental results. The observed relaxation has been attributed to fluctuations of the bond orientational order coupled to the molecular tilt. A parameter describing the softening of this mode is determined by fitting theoretical results to the experimental data. The model also describes an observed anomalous increase in the spontaneous polarization as a result of the change in the strength of bond orientational order when passing to the SmI* phase.