화학공학소재연구정보센터
Journal of Chemical Physics, Vol.110, No.13, 6491-6499, 1999
Wetting by polymers of a liquid-liquid interface: Effects of short-range interactions and of chain stiffness
The behavior of both flexible and semiflexible polymers near a liquid-liquid interface is investigated with the aid of the self-consistent-field theory as developed by Scheutjens and Fleer. A ternary system (A/B-N/C) is studied near the wetting transition. In a symmetric system, i.e., chi(AB) = chi(BC) = chi, a change in the interaction parameter chi introduces a wetting transition. The ratio of the interfacial width xi of the binary A/C system and the coil size of the polymer determines the order of this transition. Beyond a certain chain length N-c (at fixed xi) the wetting transition is of first order, whereas it is of second order for N