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Applied Catalysis A: General, Vol.193, No.1-2, 285-290, 2000
The kinetics of stereoselective hydrogenation of (-)-menthone and (+)-isomenthone mixture using nickel catalysts
The kinetics of the catalytic hydrogenation of optically active mixture of (-)-menthone and (+)-isomenthone was studied. Raney nickel and Ni/SiO2 were used as catalysts. Catalysts modified with tartaric acid (TA) were tested as well. Various isomers were produced in these reactions, especially (+)-neomenthol and (+)-neoisomenthol. Small amount of (-)-menthol was produced, the yield of (-)-isomenthol was minimal. An isomerization, of(-)-menthone and (+)-isomenthone occurred during these reactions. Isomerizations among individual menthol isomers were not detectable under the given reaction conditions. Based on the acquired experimental data, a kinetic model of the Langmuir-Hinshelwood type was created. This model was further continuously adjusted and simplified as to describe the experimental data and acquire optimal kinetic model parameters.