This paper reports the synthesis and characterization of a sulfonated polymer based on hydrogenated poly(styrene-butadiene) block copolymer (HPBS). Block copolymer ionomers were prepared through sulfonation of part of the polystyrene blocks. The free acid samples (HPBS-SH), and their blends with the non-sulfonated polymer (HPBS) and polypropylene (PP) were studied. FTIR was used to confirm sulfonation. DMA and DSC analyses have shown that T-g (HPB) remains constant for all the samples studied. Glass transition temperatures of polystyrene (PS) measured through DMA present an increase of about 30 degrees C after sulfonation, diminution (up to 13 degrees C) when the amount of HPBS increases in HPBS-SH/HPBS blends and augmentation (up to 28 degrees C) as the PP content in HPBS-SH/PP blends increases. Complex impedance measurements have shown that proton conductivity of HPBS-SH was about 8 X 10(-3) Ohm(-1) cm(-1), lower values were observed generally in the case of blends. Non-isothermal crystallization of PP was studied using Avrami analysis.