This paper examines the physico-chemical properties and structural features of six alkali-soluble lignin preparations extracted with 5, 7.5, and 10% NaOH at 50 degrees C for 4-12 h from fast-growing poplar wood. The pure lignin (PL) preparations were characterized using UV, FT-IR, C-13-NMR, GPC, and alkaline nitrobenzene oxidation methods. The results showed that all the PL fractions are relatively free of associated polysaccharides and are composed of large amounts of syringyl units together with noticeable quantities of guaiacyl and fewer p-hydro-xyphenyl units. Their weight-average molecular weights ranged from 4520 to 6900 g mol(-1). Noticeable amounts of esterified p-hydroxybenzoic acids, minor quantities of esterified p-coumaric acid, and traces of both ester and ether linked ferulic acids were identified in the isolated lignin preparations. The lignin fraction, extracted with 5% NaOH at 50 degrees C for 12 h from the dewaxed fast-growing poplar wood, is composed mainly of beta-O-4 ether bonds together with small amounts of beta-beta' and beta-5 carbon-carbon linkages between the lignin structural units.