Polymer, Vol.42, No.16, 6871-6876, 2001
Controllable inter-action between cations and thermally sensitive poly(N-vinylcaprolactam-co-sodium acrylate) microgels in water
The microgels made of poly(N-vinylcaprolactam) (PVCL) and a few percent of sodium acrylate (SA) were used as a model system to study the cation induced aggregation of colloid particles. Using such microgels make the aggregation controllable and reversible because PVCL can gradually change from hydrophilic (soluble) to hydrophobic (insoluble) in water when the temperature is increased in the range 25-35 degreesC. The aggregation induced by different kinds of cations and at different temperatures was investigated by using a combination of static and dynamic laser light scattering (LLS). At temperatures lower than similar to 30 degreesC, the microgel shrinks with increasing the cation concentration due to the increase in the ionic strength and the intra-microgel complexation. The extent of the shrinking induced by different cations follows the order of Hg2+ much greater than Cu2+ > Ca2+ > Na+. At temperatures higher than similar to 32 degreesC, Ca2+ and Cu2+ can induce inter-microgel aggregation. The Ca2+ induced aggregation is essentially reversible in the heating-and-cooling cycle, but there exists a large hysteresis in the Cu2+ induced one. As expected, monovalent Na+ was not able to induce the inter-microgel aggregation The complexation between Hg2+ and carboxylic groups is so strong that the intra-microgel complexation becomes so dominant that Hg2+ was also not able to induce the inter-microgel aggregation.