화학공학소재연구정보센터
Materials Science Forum, Vol.338-3, 583-586, 2000
Disappearance of the LO-phonon line in the UV-Raman spectrum of 6H-SiC
We undertook a study of the intensities of optical vibrational modes in the Raman spectrum of 6H-SiC as a function of excitation energy between 2.4 eV and 4.9 eV. A disappearence of the LO0 mode which is the longitudinal optical mode with the highest frequency is observed at 4.38 eV. The result is explained in the framework of a bond-Raman-polarizability model for the Raman scattering cross section as due to the cancellation of the energy dependent bond-Raman polarizabilities of intra- and inter-bilayer bonds that connect the Si and C planes in SiC.