화학공학소재연구정보센터
Langmuir, Vol.17, No.3, 581-582, 2001
Micelles of an oxime-functionalized imidazolium surfactant. Reactivities at phosphoryl and sulfonyl groups
Micelles of deprotonated 1-cetyl-3-(2-oximopropyl)imidazolium chloride strongly accelerate displacements of 4-nitrophenoxide ion from 4-nitrophenyl diethyl phosphate and 4-nitrophenyl tosylate. The first-order rate constants of reactions of fully bound substrates are similar to those predicted from second-order rate constants of reactions of deprotonated 1-methyl-3-(2-oximopropyl)imidazolium chloride in water and a reasonable value of the molar volume of the micellar interfacial region.