화학공학소재연구정보센터
Journal of Power Sources, Vol.95, No.1-2, 153-161, 2001
High rate recharge of stationary VRLA batteries
The high rate charge behavior of 6 V 155 A h lead acid monoblocs of the VRLA type for stationary service, subsequent to a full discharge in 1 h to 1.60 Vpc, is described. Charging rates with an initial constant current equal to I-10, 3I(10), 7I(10) and with constant voltage of 2.25 Vpc, resulting in a peak current of 22I(10), were evaluated for their influence on the sites and magnitude of internal heating, speed of recharge and gas emission phenomena. The results indicate that recharge with an initial current in the 3I(10) to 7I(10) range and the maximum voltage limited to 2.25 Vpe appears to be a viable charging strategy. Full recharge can be achieved in 4-6 h with the temperature rise limited to 12 degreesC above ambient and the gas evolution to an equivalent of 0.41 per cell of a hydrogen-33% oxygen mixture. The thermal video imaging revealed that the loci of maximum internal heating reflect the IR drop and the heat loss through top lead and monobloc walls. (C) 2001 Elsevier Science B.V. All rights reserved.