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Journal of Physical Chemistry B, Vol.105, No.7, 1494-1502, 2001
Modeling the electrical behavior of an alkaline hydrogen peroxide generating flow-through electrochemical reactor
Two limiting-case simplified models of mass- and charge-transport phenomena in a flow-through electrochemical reactor were developed. It is postulated that the true experimental system's behavior falls in between. The models account for energy loss due to the ohmic drop, forced convection, diffusion, and migration. The calculation results were compared against experimental data.