Catalytic reductions of 6-bromo-1-hexene and (R)-(-)-citronellyl bromide with Ni(I) complexes, electrogenerated from Ni(II) complexes, in N,N ' -dimethylformamide have been investigated with the aid of cyclic voltammetry and controlled-potential electrolyses. Cyclic compounds are obtained in appropriate experimental conditions. The influence of a proton donor and a hydrogen atom donor on the system is described.