Surface Acidic Properties of BaO-SiO2 Mixed Oxide Catalyst and Activity for Acid Catalysis

Jong Rack Sohn; Hae Won Kim; Young Il Pae

Journal of Industrial and Engineering Chemistry, Vol.7, No.3, 160-166, May, 2001

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Surface Acidic Properties of BaO-SiO2 Mixed Oxide Catalyst and Activity for Acid Catalysis

Jong Rack Sohn^†, Hae Won Kim¹, and Young Il Pae²

Department of Industrial Chemistry, Engineering College, Kyungpook National Univ., Taegu 702-701, Korea
¹Department of Industrial Chemistry, Kyungil University, Kyungsan 712-701, Korea
²Department of Chemistry, University of Ulsan, Ulsan 680-749, Korea

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A series of BaO-SiO2 catalysts were prepared by coprecipitation from the mixed solution of barium chloride and sodium silicate. The addition of BaO to SiO2 caused the increase of acidity and the shift of O-H and Si-O stretching bands of the silanol group to a lower frequency in proportion to the BaO content, The acid structure of BaO-SiO2 agreed with that proposed by Tanabe and coworkers. Catalytic activity for 2-propanol dehydration and cumene dealkylation increased in relation to the increase of acidity and band shift to a lower frequency.

Keywords:BaO-SiO2 Catalyst;Acidic Properties;2-Propanol Dehydration;Cumene Dealkylation;Acid Structure

[References]

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Davis RJ, Liu Z, Chem. Mater., 9, 2311 (1997)
Sohn JR, Jang HJ, J. Catal., 132, 563 (1991)
Doh IJ, Pae YI, Sohn JR, J. Ind. Eng. Chem., 5(3), 161 (1999)
Fung J, Wang I, J. Catal., 164(1), 166 (1996)
Maksimov GM, Fedotov MA, Bogdanov SV, Litvak GS, Golovin AV, Likholobov VA, J. Mol. Catal. A-Chem., 158, 435 (2000)
Contescu C, Popa VT, Miller JB, Ko EI, Schwarz JA, Chem. Eng. J., 64, 265 (1996)
Scheithauer M, Grasselli RK, Knozinger H, Langmuir, 14(11), 3019 (1998)
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Itoh M, Hattori H, Tanabe K, J. Catal., 35, 225 (1974)
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Hino M, Arata K, J. Chem. Soc.-Chem. Comm., 851 (1980)
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Scheithauer M, Cheung TK, Jentoft RE, Grasselli RK, Gates BC, Knozinger H, J. Catal., 180(1), 1 (1998)
Sohn JR, Kim HJ, J. Catal., 101, 428 (1986)
Sohn JR, Kim HW, Kim JT, J. Mol. Catal., 41, 375 (1987)
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Sohn JR, Ryu SG, Langmuir, 9, 126 (1993)
Tanabe K, Misono M, Ono Y, Hattori H, in New Solid Acids and Bases Kodansha, Tokyo (1989)
Sohn JR, Ozaki A, J. Catal., 61, 29 (1980)
Stubican V, Roy R, Kristallogr., 115, 200 (1961)
Sohn JR, Ozaki A, J. Catal., 59, 303 (1979)
Farmer VC, Russell JD, Spectrochim. Acta, 20, 1149 (1964)
Sohn JR, Jang HJ, Park MY, Park EH, Park SE, J. Mol. Catal., 93, 149 (1994)
Boccuzzi F, Coluccla S, Ghiotti G, Mortterra C, Zecchina A, J. Phys. Chem., 82, 1298 (1978)
Sohn JR, Jang HJ, J. Mol. Catal., 64, 349 (1991)
Peri JB, J. Phys. Chem., 70, 2937 (1966)
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Baiker A, Dollenmeier P, Glinski M, Reller A, Sharma VK, J. Catal., 111, 273 (1988)
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[Referenced By]

[1] Bosman HJ, Kruissink EC, Vanderspoel J, Vandenbrink F, J. Catal., 148(2), 660 (1994)

[2] Davis RJ, Liu Z, Chem. Mater., 9, 2311 (1997)

[3] Sohn JR, Jang HJ, J. Catal., 132, 563 (1991)

[4] Doh IJ, Pae YI, Sohn JR, J. Ind. Eng. Chem., 5(3), 161 (1999)

[5] Fung J, Wang I, J. Catal., 164(1), 166 (1996)

[6] Maksimov GM, Fedotov MA, Bogdanov SV, Litvak GS, Golovin AV, Likholobov VA, J. Mol. Catal. A-Chem., 158, 435 (2000)

[7] Contescu C, Popa VT, Miller JB, Ko EI, Schwarz JA, Chem. Eng. J., 64, 265 (1996)

[8] Scheithauer M, Grasselli RK, Knozinger H, Langmuir, 14(11), 3019 (1998)

[9] Hucknall DJ, in Selective Oxidation of Hydrocarbons Academic Press, London/New York (1974)

[10] Itoh M, Hattori H, Tanabe K, J. Catal., 35, 225 (1974)

[11] Tanabe K, Ishiya G, Ichikawa I, Hattori H, Bull. Chem. Soc. Jpn., 45, 47 (1972)

[12] Vogt ETC, Boot A, van Dillen AJ, Geus JW, Janssen FJJG, van der Kerkhof FMG, J. Catal., 114, 313 (1988)

[13] Dzisko VA, in Proc. Inertn. Congr. Catalysis 3rd ed., Amsterdam, Vol. 1, No. 19 (1964)

[14] Sohn JR, Jang HJ, Park MY, Park EH, Park SE, J. Mol. Catal., 93, 149 (1994)

[15] Tanabe K, Seiyama T, Hucki K, in Metal oxide and Mixed oxides, Kodansha, Tokyo (1978)

[16] Barton DG, Shtein M, Wilson RD, Soled SL, Iglesia E, J. Phys. Chem. B, 103(4), 630 (1999)

[17] Hino M, Arata K, J. Chem. Soc.-Chem. Comm., 851 (1980)

[18] Hino M, Kobayashi S, Arata K, J. Am. Chem. Soc., 101, 6439 (1979)

[19] Scheithauer M, Cheung TK, Jentoft RE, Grasselli RK, Gates BC, Knozinger H, J. Catal., 180(1), 1 (1998)

[20] Sohn JR, Kim HJ, J. Catal., 101, 428 (1986)

[21] Sohn JR, Kim HW, Kim JT, J. Mol. Catal., 41, 375 (1987)

[22] Sohn JR, Kim HW, J. Mol. Catal., 52, 361 (1989)

[23] Sohn JR, Ryu SG, Langmuir, 9, 126 (1993)

[24] Tanabe K, Misono M, Ono Y, Hattori H, in New Solid Acids and Bases Kodansha, Tokyo (1989)

[25] Sohn JR, Ozaki A, J. Catal., 61, 29 (1980)

[26] Stubican V, Roy R, Kristallogr., 115, 200 (1961)

[27] Sohn JR, Ozaki A, J. Catal., 59, 303 (1979)

[28] Farmer VC, Russell JD, Spectrochim. Acta, 20, 1149 (1964)

[29] Sohn JR, Jang HJ, Park MY, Park EH, Park SE, J. Mol. Catal., 93, 149 (1994)

[30] Boccuzzi F, Coluccla S, Ghiotti G, Mortterra C, Zecchina A, J. Phys. Chem., 82, 1298 (1978)

[31] Sohn JR, Jang HJ, J. Mol. Catal., 64, 349 (1991)

[32] Peri JB, J. Phys. Chem., 70, 2937 (1966)

[33] Riva A, Trifiro F, Vaccari A, Mintchev L, Busca G, J. Chem. Soc.-Faraday Trans., 84, 1423 (1988)

[34] Baiker A, Dollenmeier P, Glinski M, Reller A, Sharma VK, J. Catal., 111, 273 (1988)

[35] Miura M, Kubota Y, Iwaki T, Takimoto K, Muraoka Y, Bull. Chem. Soc. Jpn., 42, 1476 (1969)

[36] Sohn JR, Cho HS, Kim HW, J. Ind. Eng. Chem., 5(1), 1 (1999)

[37] Park Y, Kim J, Choi HJ, J. Ind. Eng. Chem., 6(6), 431 (2000)

[38] Johnson O, J. Phys. Chem., 59, 827 (1955)