알루미늄 엣칭부산물을 이용한 NBR 재료의 난연성 및 내열성

김경환; 이창섭; Kyung Hwan Kim; Chang Seop Ri

Journal of the Korean Industrial and Engineering Chemistry, Vol.11, No.8, 855-860, December, 2000

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알루미늄 엣칭부산물을 이용한 NBR 재료의 난연성 및 내열성

Flame Retardency and Thermal Resistance of NBR Materials Using Aluminum Etching Byproduct

김경환, 이창섭^†

계명대학교 화학과, 대구 704-701

Kyung Hwan Kim, and Chang Seop Ri^†

Department of Chemistry, Keimyung University, Daegu 704-701, Korea

E-mail:

초록

가공한 알루미늄 엣칭 부산물을 자동차용 호스의 구성재료인 아크릴로니트릴부타디엔고부(NBR)에 첨가하여 NBR 배합고무의 가황 특성, 물성, 내열 및 난연 특성을 측정하였으며, 실험결과로부터 고무와 첨가제의 최적배합조건을 도출하였다. 알루미늄 표면처리 공정에서 발생되는 엣칭 부산물은 분쇄와 정제를 거쳐 수산화알루미늄으로 가공하였으며, 내열 및 난연제로서 NBR에 0∼80 phr 범위에서 배합하고, 고무시편의 경도, 인장강도, 신장율 및 난연성을 측정한 결과, 고무재료 규격을 초과하지 않는 범위내에서 최대의 내열 및 난연효과를 주는 수산화알루미늄의 첨가량은 40 phr로 나타났으며, 이 배합비에서 NBR의 난연성은 5배 정도 향상되었다.

The by-product of aluminum etching process was added to acrylonitrile butadiene rubber (NBR), which is the construction material of automotive hose. Cure characteristics, physical properties, thermal resistance and flame retardency of NBR compounds were measured, and optimum mixing ratio of rubber and additives was deduced from the experimental results. The by-product of etching, produced in the process of surface treatment of aluminum, was converted to aluminum hydroxide through crushing and purification. This was then mixed to NBR as a thermal and flame retardent within the range of 0∼80 phr. Thermal resistance and flame retardency as well as other characteristics and physical properties of compounded rubber specimens were measured. The optimum mixing ratio of rubber to additives to give maximum effect on thermal resistance and flame retardency, within the range of tolerable specification for rubber materials, was determined to be 40 phr, and at this mexing ratio, the flame retardency of NBR was found to be increased by 5 times.

Keywords:Flame retardency;Fire resistance;Acrylonitrile butadiene rubber(NBR);Etching byproduct;Aluminum hydroxide

[References]

Lewin M, Atlas SM, Pearce EM, "Flame Retardant Polymeric Materials," 1, 187, Plenum Press, New York (1975)
Kim DK, Seul SD, Sohn JE, J. Korean Ins. Rubber Ind., 22, 324 (1987)
Moon DJ, Kim DK, Seul SD, J. Korean Ins. Rubber Ind., 24, 11 (1989)
Lee JU, Kim WK, Kim BH, J. Korean Ins. Rubber Ind., 21, 121 (1986)
Quirk RP, Rubber Chem. Technol., 57, 557 (1984)
Cesca S, Polym. Sci., 32, 1 (1979)
Barnard D, Kautsch. Gummi Kunstst., 35, 747 (1982)
Shin DW, Hong CS, J. Korean Ins. Rubber Ind., 30(4) (1995)
Cho WJ, J. Korean Ins. Rubber Ind., 30(4) (1995)
Ranney MW, Sollman KJ, Pickwell RJ, Rubber Chem. Technol., 45, 1166 (1972)
Ssrille B, Watson AA, Rubber Chem. Technol., 40, 100 (1967)
Trelonr LRG, Rubber Chem. Technol., 47, 625 (1974)
Wood LA, Rubber Chem. Technol., 53, 116 (1980)
Llorente MA, Mark JE, Rubber Chem. Technol., 53, 988 (1980)
Medalia AI, Rubber Chem. Technol., 54, 437 (1980)
KS M 6518, 가황고무 물리시험방법
Holden G, Legge NR, Quirk R, Schroeder HE, Thermoplastic Elastomers, 1, Hanser/Gardner (1996)
Jin JY, Kim HS, Choi SY, J. Korean Ins. Rubber Ind., 30, 1 (1995)
Jana PB, De SK, Polym. Commun., 32, 376 (1991)

[Referenced By]

[1] Lewin M, Atlas SM, Pearce EM, "Flame Retardant Polymeric Materials," 1, 187, Plenum Press, New York (1975)

[2] Kim DK, Seul SD, Sohn JE, J. Korean Ins. Rubber Ind., 22, 324 (1987)

[3] Moon DJ, Kim DK, Seul SD, J. Korean Ins. Rubber Ind., 24, 11 (1989)

[4] Lee JU, Kim WK, Kim BH, J. Korean Ins. Rubber Ind., 21, 121 (1986)

[5] Quirk RP, Rubber Chem. Technol., 57, 557 (1984)

[6] Cesca S, Polym. Sci., 32, 1 (1979)

[7] Barnard D, Kautsch. Gummi Kunstst., 35, 747 (1982)

[8] Shin DW, Hong CS, J. Korean Ins. Rubber Ind., 30(4) (1995)

[9] Cho WJ, J. Korean Ins. Rubber Ind., 30(4) (1995)

[10] Ranney MW, Sollman KJ, Pickwell RJ, Rubber Chem. Technol., 45, 1166 (1972)

[11] Ssrille B, Watson AA, Rubber Chem. Technol., 40, 100 (1967)

[12] Trelonr LRG, Rubber Chem. Technol., 47, 625 (1974)

[13] Wood LA, Rubber Chem. Technol., 53, 116 (1980)

[14] Llorente MA, Mark JE, Rubber Chem. Technol., 53, 988 (1980)

[15] Medalia AI, Rubber Chem. Technol., 54, 437 (1980)

[16] KS M 6518, 가황고무 물리시험방법

[17] Holden G, Legge NR, Quirk R, Schroeder HE, Thermoplastic Elastomers, 1, Hanser/Gardner (1996)

[18] Jin JY, Kim HS, Choi SY, J. Korean Ins. Rubber Ind., 30, 1 (1995)

[19] Jana PB, De SK, Polym. Commun., 32, 376 (1991)