Reversibility and Linearity of Sorption for Some Cations onto a Bulguksa Granite

Chung-Kyun Park; Pil-Soo Hahn

Korean Journal of Chemical Engineering, Vol.16, No.6, 758-763, November, 1999

DOI10.1007/BF02698348 Export Citation

Reversibility and Linearity of Sorption for Some Cations onto a Bulguksa Granite

Chung-Kyun Park^†, and Pil-Soo Hahn

Radioactive-waste Disposal Research Team, Korea Atomic Energy Research Institute, USA

E-mail:

Sorption experiments for Co-60, Sr-85, and Cs-137 Onto a Bulguksa granite were carried out to investigate the migration mobility. Reversibility and Linearity of sorption as well as sorption mechanism were examined. Sorption isotherms were fitted in the range of 10(-3) M and 10(-11) M and the applicability of the two isotherm equations, Langmuir and Freundlich, was examined. Sr-85 give rise to almost linear isotherms, while Co-60 and Cs-137 show nonlinear behavior. In order to distinguish sorption types of the cations, a sequential chemical extraction was introduced. The sorbed cations were extracted by applying different solutions of synthetic groundwater CaCl2, KCl, and KTOX(K2C2O4+NH2OH-HCl). Sorption types considered are reversible sorption under a groundwater condition, ion exchange, association with ferro-manganese oxides, and irreversible fixation.

Keywords:Sorption Reversibility;Sorption Linearity;Sorption Isotherm;Sequential Chemical Extraction;Surface Complexation Model

[References]

Adamson AW, "Physical Chemistry of Surfaces," Chap. 11, John Wiley & Sons (1982)
Anderson K, "Transport of Radionuclides in Water/Mineral Systems," Chalmers Univ. of Tech. (1983)
Clark S, Johnson W, Malek M, Serkiz S, Hinton T, Radiochim. Acta, 74, 173 (1996)
Cho YH, Park CK, Hahn PS, J. Korean Nucl. Soc., 29 (1997)
Davis JA, Kent DB, Rev. Mineralogy, 23, 177 (1990)
Evans D, Alberts J, Clark R, Geochim. Cosmochim. Acta, 47, 1041 (1983)
Means J, Crerar D, Borcsil M, Geochim. Cosmochim. Acta, 42, 1763 (1978)
Murray J, Geochim. Cosmochim. Acta, 39, 505 (1975)
Park CK, Woo SI, Tanaka T, Kamiyama K, J. Nucl. Sci. Technol., 29, 176 (1992)
Park CK, Vandergraaf T, Hahn PS, J. Cont. Hydrology, 26, 97 (1997)
Park CK, Keum DK, Hahn PS, Korean J. Chem. Eng., 12(4), 428 (1995)
Park CK, Hahn PS, HWAHAK KONGHAK, 35(4), 463 (1997)
Park CK, Cho YH, Hahn PS, J. Korean Solid Wastes Eng. Soc., 14(5), 412 (1997)
Skagius K, Neretnieks I, Water Res., 24, 75 (1988)
Skagius K, Svedberg G, Neretnieks I, Nucl. Technol., 59, 302 (1982)
Stumm W, Morgan JJ, "Aquatic Chemistry," Chap. 10, 2nd Ed., Wiley Interscience Publication, NY (1981)
Tessier A, Campell P, Bission M, Anal. Chem., 51, 844 (1979)
Torstenfelt T, Andersson K, Allard B, Chem. Geology, 36, 123 (1982)
Walton FW, Melnyk T, Ross J, Skeet A, ACS Symp. Ser., 246, 45 (1984)

[Referenced By]

[1] Adamson AW, "Physical Chemistry of Surfaces," Chap. 11, John Wiley & Sons (1982)

[2] Anderson K, "Transport of Radionuclides in Water/Mineral Systems," Chalmers Univ. of Tech. (1983)

[3] Clark S, Johnson W, Malek M, Serkiz S, Hinton T, Radiochim. Acta, 74, 173 (1996)

[4] Cho YH, Park CK, Hahn PS, J. Korean Nucl. Soc., 29 (1997)

[5] Davis JA, Kent DB, Rev. Mineralogy, 23, 177 (1990)

[6] Evans D, Alberts J, Clark R, Geochim. Cosmochim. Acta, 47, 1041 (1983)

[7] Means J, Crerar D, Borcsil M, Geochim. Cosmochim. Acta, 42, 1763 (1978)

[8] Murray J, Geochim. Cosmochim. Acta, 39, 505 (1975)

[9] Park CK, Woo SI, Tanaka T, Kamiyama K, J. Nucl. Sci. Technol., 29, 176 (1992)

[10] Park CK, Vandergraaf T, Hahn PS, J. Cont. Hydrology, 26, 97 (1997)

[11] Park CK, Keum DK, Hahn PS, Korean J. Chem. Eng., 12(4), 428 (1995)

[12] Park CK, Hahn PS, HWAHAK KONGHAK, 35(4), 463 (1997)

[13] Park CK, Cho YH, Hahn PS, J. Korean Solid Wastes Eng. Soc., 14(5), 412 (1997)

[14] Skagius K, Neretnieks I, Water Res., 24, 75 (1988)

[15] Skagius K, Svedberg G, Neretnieks I, Nucl. Technol., 59, 302 (1982)

[16] Stumm W, Morgan JJ, "Aquatic Chemistry," Chap. 10, 2nd Ed., Wiley Interscience Publication, NY (1981)

[17] Tessier A, Campell P, Bission M, Anal. Chem., 51, 844 (1979)

[18] Torstenfelt T, Andersson K, Allard B, Chem. Geology, 36, 123 (1982)

[19] Walton FW, Melnyk T, Ross J, Skeet A, ACS Symp. Ser., 246, 45 (1984)