Chemical Fixation of Carbon Dioxide to Copolymers Bearing Cyclic Carbonate Group

Jeong-Yeol Moon; Han-Jin Jang; Kyung-Hoon Kim; Suk-Eun Na; Dae-Won Park; Jin-Kook Lee

Korean Journal of Chemical Engineering, Vol.16, No.6, 721-724, November, 1999

DOI10.1007/BF02698342 Export Citation

Chemical Fixation of Carbon Dioxide to Copolymers Bearing Cyclic Carbonate Group

Jeong-Yeol Moon¹, Han-Jin Jang¹, Kyung-Hoon Kim¹, Suk-Eun Na¹, Dae-Won Park^{1, †}, and Jin-Kook Lee^{1, 2}

¹Dept. of Chem. Eng., Pusan National University, Pusan, Korea
²Dept. of Polym. Sci. & Eng., Pusan National University, Pusan, Korea

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This study is related to the investigation of the chemical fixation of carbon dioxide to copolymers bearing a cyclic carbonate group and their application to polymer blends. In the synthesis of (2-oxo-1,3-dioxolan4-yl)methyl vinyl ether (OVE) from glycidyl vinyl ether (GVE) and CO2, quaternary ammonium salt catalysts showed good yield of OVE. The results with long alkyl chain and with lower accessibility showed a higher catalytic activity. Mixed catalyst of PEG-4000 and NaI showed higher catalytic activity than NaI alone. The copolymer of OVE and acrylonitrile (AN) was prepared by radical copolymerization in acetonitrile at 60 degrees C. The monomer reactivity ratios were given as r(1)(OVE)=0.36 and r(2)(AN)=1.21 in the copolymerization of OVE and AN. The films of poly(OVE-co-AN)/PVC blends were cast from DME The poly(OVE-co-AN)/PVC blends showed good miscibility over whole composition ranges.

Keywords:Chemical Fixation;Carbon Dioxide;Glycidyl Vinyl Ether;Cyclic Carbonate;Copolymer;Polymer Blends

[References]

Brandrup J, Immergut EH, "Polymer Handbook," John Wiley & Sons, New York (1989)
Inoue S, Yamazaki N, Higashi F, "Organic and Bioorganic Chemistry of Carbon Dioxide," Kodansha Ltd.,Tokyo (1982)
Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
Moon JY, Yang JG, Jung SM, Park DW, Lee JK, React. Kinet. Catal. Lett., 61(2), 315 (1997)
Nishikubo T, Kameyama A, Sasano M, J. Polym. Sci. A: Polym. Chem., 32(2), 301 (1994)
Nomura R, Ninagawa A, Matsuda H, J. Org. Chem., 45, 3735 (1980)
Odian G, "Principles of Polymerization," John Wiley & Sons, New York (1991)
Park DW, Moon JY, Yang JG, Jung SM, Lee JK, Stud. Surf. Sci. Catal., 114, 403 (1998)
Park CW, Park SW, Kaseger CF, Moon JY, Lee JB, React. Kinet. Catal. Lett., 62(2), 243 (1997)
Randall JC, "Polymer Sequence Determination-Carbon 13 NMR Method," Academic Press, New York (1977)
Rokicki G, Kuran W, Marciniak BP, Monat. Chem., 115, 205 (1984)
Starks CM, Liotta CL, Halpern M, "Phase Transfer Catalysis," Chapman & Hall, New York (1994)

[Referenced By]

[1] Brandrup J, Immergut EH, "Polymer Handbook," John Wiley & Sons, New York (1989)

[2] Inoue S, Yamazaki N, Higashi F, "Organic and Bioorganic Chemistry of Carbon Dioxide," Kodansha Ltd.,Tokyo (1982)

[3] Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)

[4] Moon JY, Yang JG, Jung SM, Park DW, Lee JK, React. Kinet. Catal. Lett., 61(2), 315 (1997)

[5] Nishikubo T, Kameyama A, Sasano M, J. Polym. Sci. A: Polym. Chem., 32(2), 301 (1994)

[6] Nomura R, Ninagawa A, Matsuda H, J. Org. Chem., 45, 3735 (1980)

[7] Odian G, "Principles of Polymerization," John Wiley & Sons, New York (1991)

[8] Park DW, Moon JY, Yang JG, Jung SM, Lee JK, Stud. Surf. Sci. Catal., 114, 403 (1998)

[9] Park CW, Park SW, Kaseger CF, Moon JY, Lee JB, React. Kinet. Catal. Lett., 62(2), 243 (1997)

[10] Randall JC, "Polymer Sequence Determination-Carbon 13 NMR Method," Academic Press, New York (1977)

[11] Rokicki G, Kuran W, Marciniak BP, Monat. Chem., 115, 205 (1984)

[12] Starks CM, Liotta CL, Halpern M, "Phase Transfer Catalysis," Chapman & Hall, New York (1994)