화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.25, No.2, 302-310, March, 2001
Export Citation
무전해 동도금 피막의 접착력 향상에 관한 연구 -PET 필름의 전처리 조건의 영향-
Adhesion Improvement of Electroless Copper Plated Layer on PET Film - Effect of Pretreatment Conditions
오경화†, 김동준1, 김성훈1
  • 중앙대학교 가정교육학과
  • 1한양대학교 섬유고분자공학과 기능성고분자신소재연구센타
Kyung Wha Oh†, Dong Jun Kim1, and Seong Hun Kim1
  • Department of Home Economics Education, Chung-Ang Unverisity, Seoul 156-756, Korea
  • 1Department of Fiber & Polymer Engineering, Center for Advanced Functional Polymers, Hanyang University, Seoul 133-791, Korea
E-mail:
초록
무전해도금법을 이용하여 구리/PET 필름 복합재료를 제조하였으며 에칭방법과 촉매액의 조성 및 acceleration 방법을 달리하여 PET 필름과 무전해도금된 구리 피막간의 접착력을 향상시키고자 하였다. HCl 용액으로 에칭된 PET 필름은 NaOH에 의한 것보다 더욱 세밀하게 에칭되어져 구리와 PET 필름간의 접착력은 향상되었으나 전자파 차폐효과는 유사한 경향을 보였다. 촉매액의 조성변화에 따른 영향을 살펴본 결과 PdCl2:SnCl2의 몰비가 1:4에서 1:16으로 증가할수록 PET 필름 위에 적층된 Pd/Sn 콜로이드 입자들의 크기가 감소하며 고르게 분포되는 경향을 보였다. 따라서 이들의 몰비가 증가할수록 구리도금이 균일하고 조밀하게 이루어져 접착력 및 차폐효과가 증가하였다. 또한 NaOH보다 HCl로 acceleration한 경우 촉매입자의 크기가 작고 더 균일하게 분포되어 우수한 접착력과 도금물성을 나타내었다.
Cu/PET film composites were prepared by electroless copper plating method. In order to improve adhesion between electroless Cu plated layer and polyester(PET) film, the effect of pretreatment conditions such as etching method and mixed catalyst composition, and accelerator was investigated. Compared to NaOH etching medium, PET film was more finely etched by HCl solution, resulting in an improvement in adhesion between Cu layer and PET film. However, there were no significant differences in electromagnetic interference shielding effectiveness as a function of etching medium. The surface morphology of Cu plated PET film revealed that Pd/Sn colloidal particles became more evenly distributed in the smaller size by increasing the molar ratio of PdCl2,SnCl2 from 1:4 to 1:16. With increasing the molar ratio of mixed catalyst, the adhesion and the shielding effectiveness of Cu plated PET film were increased. Furthermore, HCl was turned out to be a better accelerator than NaOH in order to enhance the activity of the mixed PdCl2/SnCl2 catalyst, which facilitated the formation of more uniform copper deposit on the PET film.
Keywords:polyethylene terephthalate (PET);electroless copper plating;electromagnetic interference shielding effectiveness (EMI-SE);lap shear test
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