Poly(ethylene oxide)/Poly(epichlorohydrin)/LiClO<sub>4 </sub> 복합체의 이온전도성

전성민; 문성인; 김우식; 민경은

Polymer(Korea), Vol.22, No.2, 275-284, March, 1998

Export Citation

Poly(ethylene oxide)/Poly(epichlorohydrin)/LiClO₄ 복합체의 이온전도성

Ionic Conductivity of Poly(ethylene oxide)/Poly(epichlorohydrin)/LiClO₄ Mixtures

전성민, 문성인, 김우식, 민경은

초록

리튬염을 함유하는 폴리에틸렌옥시드/폴리에피클로로히드린 블렌드의 이온전도도 및 열적 성질을 조사하였다. 20wt%의 PECH를 함유하는 PEO/PECH 블렌드는 PEO 단독계에 비해 소량의 리튬염을 첨가하더라도 PEO의 결정성이 파괴됨을 확인하였으며, PECH가 첨가됨으로서 이온전도도는 증가하지만 어느 값 이상에서는 더 이상 증가하지 앉았다.

The ionic conductivity and thermal properties of poly(ethylene oxide)/poly (epichlorohydrin) blends containing lithium perchlorate were studied. The amount of salt required for complete disruption of the PEO crystalline phase in PEG/PECH (80:20) blend was much smaller than that in the pure PEG. The ionic conductivities of the PEG-lithium salt mixtures were enhanced by adding PECH, but this was not effective at the higher content of PECH.

Keywords:Ionic Conductivity;Thermal Behavior;PEO/PECH Blends;Solid Polymer Electrolyte

[References]

MacCallum JR, Vincent CA, "Polymer Electrolyte Reviews I and II," Elsevier, New York (1987)
MacCallum JR, Vincent CA, "Polymer Electrolyte Reviews I and II," Elsevier, New York (1989)
Gotoh T, Kobunshi, 44, 56 (1995)
Morita M, Matsuda Y, Kobunshi, 44, 60 (1995)
Parker JM, Wright PV, Polymer, 14, 589 (1973)
Armand MB, Duclot M, Eur. Patent, 0013109, Prior. Fr. 7832976 (1978)
Armand MB, Jacobsen T, Electrochim. Acta, 27, 1671 (1982)
Amstrong RD, Clarke MD, Electrochim. Acta, 29, 1443 (1984)
Harris CS, Shriver DF, Ratner MA, Macromolecules, 19, 987 (1986)
Xia DW, Smid J, Solid State Ion., 14, 221 (1984)
Revillon A, Hamaide T, Polym. Bull., 6, 235 (1982)
Cowie JMG, Martin ACS, Firth AM, Br. Polym. J., 20, 247 (1988)
Caraven JR, Gilles JRM, Makromol. Chem. Rapid Commun., 7, 81 (1986)
Bouridah A, Cheradam H, Lenest JF, Solid State Ion., 15, 233 (1985)
Watanabe M, Kanba M, Shinohara I, Makromol. Chem. Rapid Commun., 2, 741 (1981)
Tsuchida E, Tsunemi K, Electrochim. Acta, 28, 591 (1983)
Spindler R, Shriver DF, Macromolecules, 19, 347 (1986)
Kelly IE, Owen JR, Steele VCH, J. Power Sources, 14, 13 (1985)
Kelly IE, Owen JR, Steele VCH, J. Electroanal. Chem., 168, 467 (1984)
Hardy LC, Shriver DF, Macromolecules, 17, 975 (1984)
Abraham KM, Alamgir M, Reynolds RK, J. Electrochem. Soc., 136, 3576 (1989)
Wieczorek W, Such K, Florjanczyk Z, Przyluski J, Electrochim. Acta, 37, 1565 (1992)
Whang WT, Yang LH, Fan YW, J. Appl. Polym. Sci., 54(7), 923 (1994)
Min KE, Chiou JS, Barlow JW, Paul DR, Polymer, 28, 1721 (1987)
Nagaoka K, Naruse H, Shinohara I, J. Polym. Sci. C: Polym. Lett., 22, 659 (1984)
Spindler R, Shriver DF, Macromolecules, 19, 347 (1986)
Hardy LC, Shriver DF, Macromolecules, 17, 975 (1984)
Watanabe M, Sanui K, Ogata N, Inoue F, Kobayashi T, Polym. J., 17, 549 (1985)
Cowie JMG, Martin CS, Polymer, 28, 627 (1987)
Munshi MZA, Owens BB, Polym. J., 20, 577 (1988)
Munshi MZA, Owens BB, Nguyen S, Polym. J., 20, 597 (1988)
Watanabe M, Nagano S, Sanui K, Ogata N, Polym. J., 18, 809 (1986)
Watanabe M, Sanui K, Ogata N, Inoue F, Kobayashi T, Ohtaki Z, Polym. J., 16, 711 (1984)
Kaplan ML, Reitman EA, Cava RJ, Polymer, 30, 504 (1989)
Lee CC, Wright PV, Polymer, 23, 681 (1982)
Payne DR, Wright PV, Polymer, 23, 690 (1982)
Siddiqui JA, Wright PV, Polym. Commun., 28, 5 (1987)
Yang H, Farrington GC, J. Polym. Sci. B: Polym. Phys., 31, 157 (1993)

[Referenced By]

[1] MacCallum JR, Vincent CA, "Polymer Electrolyte Reviews I and II," Elsevier, New York (1987)

[2] MacCallum JR, Vincent CA, "Polymer Electrolyte Reviews I and II," Elsevier, New York (1989)

[3] Gotoh T, Kobunshi, 44, 56 (1995)

[4] Morita M, Matsuda Y, Kobunshi, 44, 60 (1995)

[5] Parker JM, Wright PV, Polymer, 14, 589 (1973)

[6] Armand MB, Duclot M, Eur. Patent, 0013109, Prior. Fr. 7832976 (1978)

[7] Armand MB, Jacobsen T, Electrochim. Acta, 27, 1671 (1982)

[8] Amstrong RD, Clarke MD, Electrochim. Acta, 29, 1443 (1984)

[9] Harris CS, Shriver DF, Ratner MA, Macromolecules, 19, 987 (1986)

[10] Xia DW, Smid J, Solid State Ion., 14, 221 (1984)

[11] Revillon A, Hamaide T, Polym. Bull., 6, 235 (1982)

[12] Cowie JMG, Martin ACS, Firth AM, Br. Polym. J., 20, 247 (1988)

[13] Caraven JR, Gilles JRM, Makromol. Chem. Rapid Commun., 7, 81 (1986)

[14] Bouridah A, Cheradam H, Lenest JF, Solid State Ion., 15, 233 (1985)

[15] Watanabe M, Kanba M, Shinohara I, Makromol. Chem. Rapid Commun., 2, 741 (1981)

[16] Tsuchida E, Tsunemi K, Electrochim. Acta, 28, 591 (1983)

[17] Spindler R, Shriver DF, Macromolecules, 19, 347 (1986)

[18] Kelly IE, Owen JR, Steele VCH, J. Power Sources, 14, 13 (1985)

[19] Kelly IE, Owen JR, Steele VCH, J. Electroanal. Chem., 168, 467 (1984)

[20] Hardy LC, Shriver DF, Macromolecules, 17, 975 (1984)

[21] Abraham KM, Alamgir M, Reynolds RK, J. Electrochem. Soc., 136, 3576 (1989)

[22] Wieczorek W, Such K, Florjanczyk Z, Przyluski J, Electrochim. Acta, 37, 1565 (1992)

[23] Whang WT, Yang LH, Fan YW, J. Appl. Polym. Sci., 54(7), 923 (1994)

[24] Min KE, Chiou JS, Barlow JW, Paul DR, Polymer, 28, 1721 (1987)

[25] Nagaoka K, Naruse H, Shinohara I, J. Polym. Sci. C: Polym. Lett., 22, 659 (1984)

[26] Spindler R, Shriver DF, Macromolecules, 19, 347 (1986)

[27] Hardy LC, Shriver DF, Macromolecules, 17, 975 (1984)

[28] Watanabe M, Sanui K, Ogata N, Inoue F, Kobayashi T, Polym. J., 17, 549 (1985)

[29] Cowie JMG, Martin CS, Polymer, 28, 627 (1987)

[30] Munshi MZA, Owens BB, Polym. J., 20, 577 (1988)

[31] Munshi MZA, Owens BB, Nguyen S, Polym. J., 20, 597 (1988)

[32] Watanabe M, Nagano S, Sanui K, Ogata N, Polym. J., 18, 809 (1986)

[33] Watanabe M, Sanui K, Ogata N, Inoue F, Kobayashi T, Ohtaki Z, Polym. J., 16, 711 (1984)

[34] Kaplan ML, Reitman EA, Cava RJ, Polymer, 30, 504 (1989)

[35] Lee CC, Wright PV, Polymer, 23, 681 (1982)

[36] Payne DR, Wright PV, Polymer, 23, 690 (1982)

[37] Siddiqui JA, Wright PV, Polym. Commun., 28, 5 (1987)

[38] Yang H, Farrington GC, J. Polym. Sci. B: Polym. Phys., 31, 157 (1993)