Intramolecular cyclization of the three isomeric 1,4-disubstituted thiosemicarbazides 3(a-c) in aqueous sodium hydroxide was attempted to obtain 2,4-dihydro-4-(2-phenylethyl)-5-(isomeric pyridyl)-3H-1,2,4-triazole-3-thiones 4(a-c). Each of the three isolated triazoles was separately treated with benzyl chloride and with chloroacetic acid to furnish the corresponding benzylthio 5(a-c) and carboxymethylthio derivatives 6(a-c), respectively.