Two-, four- and six-layer Al2O3 coatings of the AISI 316 type stainless steel have been prepared by means of the Sol-Gel method. As a precursor substance aluminium isopropoxide was used, The coatings were approx. 2-3 mu m thick and had amorphous structures. The higher sintering temperature (within the range 500-850 degrees C), the lower cathode current density values, however also the lower breakdown potentials. Basing on results of EIS measurements it has been determined that the stainless steel/Al2O3 coating system may be substituted by an electrical model comprising three constant phase elements. The aluminium oxide coating heated at temperature of 500 degrees C remains stable within the period of 1000 hours exposition in the Ringer's solution.