Thin Solid Films, Vol.290-291, 211-215, 1996
Molecular-Dynamics Investigations of the Effects of Debris Molecules on the Friction and Wear of Diamond
The friction between two diamond surfaces placed in sliding contact has been investigated using molecular dynamics simulations. These simulations show that the friction between two hydrogen-terminated diamond (111) surfaces is significantly reduced when methane molecules are placed between the diamond surfaces compared to the same two surfaces in the absence of the debris, or third-body, molecules. Macroscopic experiments that have examined the friction of diamond on diamond in the presence of debris (Hayward and Field, Proc. Inst. Mech. Eng., IMechE Conf : 1 (1987) 205) show similar trends. The specific atomic-scale motions which lead to the reduced friction and to the deformation of the methane molecules are identified.