화학공학소재연구정보센터
Thin Solid Films, Vol.249, No.2, 254-265, 1994
The Effect of Ion-Bombardment on Some Properties of A-Si0.8Ge0.2-H Alloys Prepared by Ion-Beam-Assisted Reactive Evaporation
Amorphous hydrogenated silicon germanium thin films with 20% Ge content (a-Si0.8Ge0.2:H) were deposited by ion beam-assisted deposition (IBAD), using SiH4 as the source gas. Moderate ion energies of similar to 125 to 135 eV and an ion-to-atom ratio of similar to 1, produced samples with a reduced number of SiH2 and (SiH2)(n) bonding configurations, an increased hydrogen content and a decreased porosity compared with non-bombarded samples. This reduces the disorder in the a-SiGe network as well as the defect density. The preferential attachment coefficient for these films is near unity. The optical and electrical properties of the a-SiGe:H alloy have been studied as a function of the ion beam energy and the ion-to-atom ratio at the substrate. The best films had a photosensitivity of sigma(ph)/sigma(d) = 1.7 x 10(4) and E(g)= 1.65 eV. The ion beam increases the optical gap, lowers the dark conductivity and increases the electrical activation energy.