The quasi-isothermal curing of a diepoxide resin with a triamine of polyoxypropylene was studied by alternating differential scanning calorimetry (ADSC), which is a temperature modulated DSC technique. The complex heat capacity measurements allows to analyse the vitrification process at curing temperatures (T-c) below the maximum glass transition of the fully cured epoxy (T-g infinity = 85.8 degrees C). Initially, the modulus of the complex heat capacity \C-p*\, increases until a maximum (conversion between 0.42 and 0.56) and then decreases. This step is followed by an abrupt decay of \C-p*\ due to the vitrification of the system, which allows the determination of the vitrification time. This value agrees well with that determined by the partial curing method. The phase angle and out-of-phase heat capacity show an asymmetric wide peak during the vitrification process. The change in \C-p*\ at vitrification decreases with the increase of T-c becoming zero at temperature T-g infinity This epoxytriamine system shows a delay of the vitrification process respect to other model epoxy systems probably due to the presence of polyoxypropylene chains in the network. The decay of \C-p*\ during vitrification may be normalised between unity and zero by defining a mobility factor. This mobility factor has been used to simulate the reaction rate during the stage where the reaction is controlled by diffusion. The observed reaction rate is simulated by the product of the kinetic reaction rate, determined by the autocatalytic model, and the mobility factor.