Thermochimica Acta, Vol.287, No.2, 213-223, 1996
The Analysis of Temperature Modulated DSC Measurements by Means of the Linear-Response Theory
A consistent description of temperature modulated differential scanning calorimeter (TM-DSC) curves based on irreversible thermodynamics is presented within the scope of the validity of the linear response approximation. Both time-independent and time-dependent processes are included. For time-dependent (linear) processes, the heat how rate is connected to the convolution integral. This results in a generalized heat capacity which is frequency dependent and, on principle, a complex function of it.
Keywords:DIFFERENTIAL SCANNING CALORIMETRY