Thermochimica Acta, Vol.286, No.2, 387-397, 1996
Thermodynamic Relationships on Complex-Formation .3. Delta-H-Delta-S Interplay in the Equilibria for the Formation of Amine Complexes in Aqueous-Solution
Delta H-Delta S values for the protonation and complexing reaction series of amines in aqueous solution have been inspected for the occurrence of functional relationships or regular patterns. Both non-linear and anti-compensative relationships have been evidenced.