Thermochimica Acta, Vol.284, No.2, 379-387, 1996
Some Successes and Failures of the Methods Based on Several Experiments
The actual kinetics of a solid state reaction cannot be discerned by means of the kinetic analysis of a single TG curve. The cause of this relates to the fact that different kinetic equations appear to fit a set of kinetic data. This paper shows the advantage of a choice of method based on comparing data from several experiments at the same degree of conversion. But this procedure must be carried out with great care. The limitations are discussed.