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Solid State Ionics, Vol.91, No.1-2, 161-164, 1996
Brillouin-Scattering Study of the Superionic Phase-Transition in (NH4)(4)H-2(Seo4)(3)
The acoustic behaviour of (NH4)(4)H-2(SeO4)(3) single crystal around the superionic phase transition at 378 K was studied by Brillouin scattering measurements. No anomaly of the longitudinal mode in the [100] direction was observed whereas 5% softening of the longitudinal mode with a minimum at 382 K was found in the [001] direction. The possible symmetry of the crystal above the superionic phase transition is discussed.