화학공학소재연구정보센터
Rheologica Acta, Vol.36, No.6, 677-685, 1997
Inlet instabilities in the capillary flow of polyethylene melts
Inlet instabilities in the capillary flow of polyethylene melts were studied in this work. Extrudate distortions in branched polyethylenes, produced by unstable upstream flow, were found to be accompanied by pressure oscillations that do not have their origin in the slip phenomenon, but on polymer compressibility. The absence of slip was clearly evidenced in the experiments, and the differences between pressure oscillations occurring in linear and branched polymers are shown. Pressure oscillations in the capillary flow of branched polyethylenes were found to be made up of at least two components of different frequency and amplitude. These two components were identified with different bulk defects appearing in the extrudates. Information about the dynamics of vortices upstream of the contraction and extrudate distortions is obtained from the analysis of pressure oscillations. The influence of capillary entrance angle on flow curves was also investigated. From the results, it is concluded that the extensional component of the flow in the contraction is the main factor responsible for the slope change usually found in the log-log flow curves of both Linear and branched polyethylenes.