A novel method for the preparation of polypyrrole hybrids with polyamines or polyimines is described. The polyreaction is performed by using chemical oxidants, e.g., iron(III) chloride or ammonium persulfate in acidic solution. The polymer hybrids are soluble in water and have a good processability. H-1-NMR, C-13-NMR, UV-Vis, IR spectroscopy and thermal gravimetric analysis was used for characterization. The physical and chemical properties of the polymer hybrids prepared are compared with those of polypyrrole and the polymeric precursor amine.