The synthesis and investigation are reported for the phase behavior of a set of three liquid-crystalline side chain polyesters (SCLCPs), consisting of aromatic diacids and diols bearing cyano biphenyl moieties in the side chain. The materials contain a chiral center in the main chain and show a cholesteric phase Indicative of a helical order with a preferred twist. In addition, they exhibit T-g’s below room temperature and smectic bilayer phases. Depending on the substitution pattern of the aromatic core, S-C* or S-A, phases are observed. These polymers were synthesized in a four-step synthesis, starting from available materials. The dielectric relaxation behavior and the pyroelectric responses of the three SCLCPs tend to conform to their respective structure.