Polymer Engineering and Science, Vol.34, No.4, 318-329, 1994
Deformation and Entanglement in Semicrystalline Polymers
Transmission electron microscopy and optical studies of thin films of isotactic polystyrene (iPS) and polyoxymethylene (POM) provide evidence for a distinction between crazing mechanisms in semicrystalline polymers above and below T(g). In the latter temperature regime, deformation in iPS and POM crystallized at high supercooling has been discussed in terms of existing models for crazing in amorphous glassy polymers, based on entanglement ideas. Above T(g), where the difference in mechanical behavior of the amorphous and crystalline regions becomes marked, the fibrillar nature of local deformation appears to be a consequence of the inhomogeneity of the undeformed polymer.
Keywords:GLASSY-POLYMERS;ISOTACTIC POLYSTYRENE;THIN-FILMS;CRYSTALLIZATION;BEHAVIOR;POLYETHERSULFONE;DISENTANGLEMENT;MICROSTRUCTURE;POLYCARBONATE;MORPHOLOGY