Ion conducting polyurethane electrolyte with redox active ferrocene groups which are fixed to the polymer backbone by covalent bonds was prepared. It has been found that the resulting polyurethane electrolyte has high conductivity even at lower temperature. And the temperature dependence of conductivity follows well the Arrhenius equation. Solid state electrochemical property was measured by cyclic voltammetric method with microdisk electrodes at different temperature. The results indicated that the polyurethane electrolyte has good redox stability, as well as reiteration, and show electrochemical activity in the solid slate.