화학공학소재연구정보센터
Polymer Bulletin, Vol.37, No.2, 183-189, 1996
Reactive Surfactants in Heterophase Polymerization .3. Poly(Ethylene Oxide) Macromonomers and Polymerizable Surfactants (Surfmers) as Stabilizers in Styrene Dispersion Polymerization
Maleic, Styrenic and Methacrylic macromonomers of poly(ethylene oxide) and related polymerizable surfactants (SURFMERS) have been used as stabilizers in the dispersion polymerization of styrene in ethanol-water mixtures. The current study looks at the polymerization yield, the particle size and the incorporation yield of the stabilizers onto the surface of the particles. The macromonomers are better suited than the corresponding SURFMERS for steric stabilization of the particles.