Polymer, Vol.38, No.17, 4491-4497, 1997
Cross-Linking and Drying of a 2-Component Waterborne Coating Monitored by a Functionalized Charge-Transfer Fluorescence Probe
A donor-bridge-acceptor fluorophore with extreme sensitivity to environmental influences has been attached covalently to a polyamino crosslinker. It was found that the progress of the crosslinking reaction with an aceto-acetate functionalized polyacrylate dispersion can be monitored from the fluorescence wavelength shift of the fluorophore. Also formation and drying of films applied from the resulting labelled dispersion induces a significant wavelength shift of the fluorescence of the incorporated label.
Keywords:ACCEPTOR SYSTEMS;SOLID-STATE;POLYMERIZATION;1-PHENYL-4-((4-CYANO-1-NAPHTHYL)METHYLENE)PIPERIDINE