화학공학소재연구정보센터
Polymer, Vol.34, No.18, 3774-3777, 1993
Theory of Isotropic-Nematic Phase-Transition in Nematic Block-Copolymers
A model is suggested to treat nematic block copolymers with mesogenic groups in the main chains. It is based on a mean-field approach taking into account attractive interactions between chain segments, and allows the description of chains with varying flexibility (with somewhat flexible mesogens). The free energy is calculated; it yields the behaviour of the temperature-dependent nematic-isotropic phase transition in the system for various sets of parameters (concentration of the two components and constants of anisotropic interaction).