화학공학소재연구정보센터
Particle & Particle Systems Characterization, Vol.16, No.6, 249-256, 1999
The fundamentals of particle size analysis by transmission fluctuation spectrometry part 1: A theory of temporal transmission fluctuations in dilute suspensions
The extinction of radiation in suspensions is traditionally described by the Bouger-Lambert-Beer law (BLBL). Based on a quasicontinuum approach, the BLBL does not account for the discrete nature of particles or their spatial extension and arrangement. If an extinction measurement is made with a high spatial and temporal resolution, the transmitted intensity signal shows significant fluctuations. The strength of fluctuation is related to the physical properties of the suspension and the process of spatial and temporal averaging. Exploiting this connection, it is possible to calculate the particle size distribution and the particle concentration from transmission measurements. This part of the series of papers provides a method for the temporal decomposition of the transmission's power spectrum, which permits the information on the particle size and concentration to be extracted from the seemingly irregular fluctuation of the transmission signal.