Following the discovery of stishovite (the highest-pressure polymorph of silica known from natural samples), many attempts have been made to investigate the possible existence of denser phases of silica at higher pressures. Based on the crystal structures observed in chemical analogues of silica(1-3), high-pressure experiments on silica(4-11) and theoretical studies(12-16), several possible post-stishovite phases have been suggested, But the likely stable phase of silica at pressures and temperatures representative of Earth’s lower mantle remains uncertain, Here we report the results of an X-ray diffraction study of silica that has been heated to temperatures above similar to 2,000 K and maintained at pressures between 68 and 85 GPa. We observe the occurrence of a new high-pressure phase which we identify with the aid of first-principles total-energy calculations, The structure of this phase (space group Pnc2) is intermediate between the alpha-PbO2 and ZrO2 structures, and is denser than other known silica phases.