Ferromagnetic Interaction in a Pyrimidine-Bridged Copper(II) Nitrate Complex

Nakayama K; Nakagawa M; Ishida T; Ishikawa Y; Yasui M; Iwasaki F; Nogami T

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.306, 379-384, 1997

DOI10.1080/10587259708044590 Export Citation

Ferromagnetic Interaction in a Pyrimidine-Bridged Copper(II) Nitrate Complex

Nakayama K, Nakagawa M, Ishida T, Ishikawa Y, Yasui M, Iwasaki F, Nogami T

Linear polymeric complexes [PM2.Cu(NO3)(2)](n) (PM = pyrimidine) and [L.Cu(hfac)(2)](n) (L = PM, 4- and 5-methylpyrimidine, and quinazoline) have been synthesized and characterized. The copper(II) spins were ferromagnetically coupled for all cases.

Keywords:INTRAMOLECULAR MAGNETIC INTERACTION;TRANSITION-METAL COMPLEXES;SPIN POLARIZATION;POLYRADICALS;LIGAND