Applied Catalysis A: General, Vol.172, No.2, 225-232, 1998
Ultrasonic irradiation as activity and selectivity improving factor in the hydrogenation of cinnamaldehyde over Pt/SiO2 catalysts
The effect of ultrasounds on the platinum-catalyzed hydrogenation of cinnamaldehyde was studied in the liquid phase over Pt/SiO2, Pt/Al2O3, Pt/C and EuroPt-1 catalysts under mild experimental conditions (333 K, 1 atm H-2). The sonochemical pretreatment was found to be highly beneficial for the selective formation of cinnamyl alcohol (up to 80%) over silica-supported catalysts, besides the significant reaction rate increase (two-fold increase). The actual changes of the catalysts were studied by transmission electron microscopy, and the mechanistic interpretation of the sonochemical effect is also given.
Keywords:RING-OPENING REACTIONS;METAL-CATALYSTS;ALPHA;BETA-UNSATURATEDALDEHYDES;RUTHENIUM CATALYSTS;PLATINUM CATALYSTS;PROPYLCYCLOBUTANE;CHEMOSELECTIVITY;CROTONALDEHYDE;ADSORPTION;ACROLEIN