Spectroscopic and Bulk Susceptibility Evidence for Independent Antiferromagnetic Ordering Transitions in the Rock-Salt Like Structured Heterobimetallic Complexes (Cr(NH3)(6))(Fecl6) and (Ru(NH3)(6))((Fecl6)) - Consequences of Highly Different Magnetic Symmetries

Reiff WM; Hatfield WE

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.273, 33-40, 1995

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Spectroscopic and Bulk Susceptibility Evidence for Independent Antiferromagnetic Ordering Transitions in the Rock-Salt Like Structured Heterobimetallic Complexes (Cr(NH3)(6))(Fecl6) and (Ru(NH3)(6))((Fecl6)) - Consequences of Highly Different Magnetic Symmetries

Reiff WM, Hatfield WE

Entirely separate 3D-A.F. magnetic ordering processes are observed for the ionic components of the rock salt like materials [Cr(NH3)(6)][FeCl6] and [Ru(NH3)(6)][FeCl6] through high resolution a.c. susceptibility and Mossbauer spectroscopy measurements.

Keywords:MOSSBAUER-SPECTROSCOPY