화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.256, 909-914, 1994
Raman-Study of Phase-Transitions in C-70 Crystal at High-Pressure
The Raman spectra of C70 Single crystals have been measured at pressures up to 17 GPa. The frequency Omega of most of the optical intramolecular phonons increases linearly with pressure P. The slope of the pressure shift d Omega/dP itself has jumps at 2+/-0.2 and 5.5+/-0.5 GPa. These jumps are correlated with a sharp change in the half-width of the Raman line for several optical modes. The peculiarities of the Raman scattering are linked with phase transitions caused by an orientational ordering of the C70 molecules in the crystal lattice as the pressure is raised.