Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.256, 885-890, 1994
Spectroscopic Study of Fluctuations of Kinks Photoinduced in an MX Chain Complex
We report the experimental results on the temperaturte dependence of the photoinduced midgap absorption bands in [Pt(en)(2)][Pt(en)(2)Cl-2](ClO4)(4). The behaviors of the spectral position and line shape of the A band are found to be explained well in terms of the quantum fluctuation and translational motion of solitons.
Keywords:EN = ETHYLENEDIAMINE;OPTICAL-ABSORPTION;METAL-COMPLEXES;RESONANCE RAMAN;MIDGAP STATES;(PT(EN)2)(PT(EN)2CL2)(CLO4)4;SPECTRA;MOTION;SHAPE;MODEL