Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.242, 221-226, 1994
Solid-State Photochromism and Thermochromism of N-(5-Bromosalicylidene)-2-Phenylethylamine
The title compound exhibits in its crystalline state both photochromic and thermochromic properties. The crystal structure shows that the salicylaldimino part is planar to permit enol - keto isomerization and thus thermochromism. Moreover, the crystal packing permits the cis - trans isomerization of the keto species to form the photoproduct.